Short but good article from VMWorld 2011 #GD21 - vSphere Guest OS Partition Alignment http://blogs.vmware.com/vsphere/2011/08/guest-os-partition-alignment.html So we have Windows Vista, 7, Server 2008, RHEL/CentOS 6 that aligns automatically. W2K3 doesn't!
Links, commands and settings I someday probably won't find again